Alkyne Hydroheteroarylation: Enantioselective Coupling of Indoles and Alkynes via Rh-Hydride Catalysis.
نویسندگان
چکیده
We report an enantioselective coupling between alkynes and indoles. A Rh-hydride catalyst isomerizes alkynes to generate a metal-allyl species that can be trapped with both aromatic and heteroaromatic nucleophiles.
منابع مشابه
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 139 31 شماره
صفحات -
تاریخ انتشار 2017